An isolable linear aminoborylene: A dicoordinate cyclic alkyl(amino)carbene (CAAC)-stabilized aminoborylene isoelectronic with an allene undergoes intramolecular C−C bond activation under photolytic conditions, intramolecular aryl migration in the presence of acetonitrile, one-electron oxidation with copper(I) halides to the corresponding haloboryl radicals, transition-metal-like binding of CO and reduction of N₂O, sulfur and selenium, the latter yielding a terminal boraselenone.

中文翻译：

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线性氨基硼烯的 C−C 和 C−N 键激活、路易斯碱配位和单电子和双电子氧化

一种可分离的线性氨基硼烯：双配位环烷基（氨基）卡宾（CAAC）稳定的氨基硼烯等电子与丙二烯在光解条件下经历分子内 C−C 键活化，在乙腈存在下分子内芳基迁移，用铜单电子氧化（ I) 卤化到相应的卤硼基自由基，CO 的过渡金属样结合和 N ₂ O、硫和硒的还原，后者产生末端硼硒酮。