Tunable Latency of Hydrosilylation Catalyst by Ligand Density on Nanoparticle Supports,Angewandte Chemie International Edition

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Tunable Latency of Hydrosilylation Catalyst by Ligand Density on Nanoparticle Supports
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-01 , DOI: 10.1002/anie.202214267
Susannah A Miller ₁ , Damien Guironnet ₁

Affiliation

The density of norbornene ligands on silica nanoparticles alters the activity of a Pt hydrosilylation catalyst. Latency of hydrosilylation at high ligand density occurs despite the non-inhibitory behavior of the free ligand and establishes the non-innocent role of functionalized inorganic supports.

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