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From Subaging to Hyperaging in Structural Glasses
Physical Review Letters ( IF 8.1 ) Pub Date : 2022-11-30 , DOI: 10.1103/physrevlett.129.238003 Luis F Elizondo-Aguilera 1 , Tommaso Rizzo 2, 3 , Thomas Voigtmann 4, 5
Physical Review Letters ( IF 8.1 ) Pub Date : 2022-11-30 , DOI: 10.1103/physrevlett.129.238003 Luis F Elizondo-Aguilera 1 , Tommaso Rizzo 2, 3 , Thomas Voigtmann 4, 5
Affiliation
We demonstrate nonequilibrium scaling laws for the aging and equilibration dynamics in glass formers that emerge from combining a relaxation equation for the static structure with the equilibrium scaling laws of glassy dynamics. Different scaling regimes are predicted for the evolution of the structural relaxation time with age (waiting time ), depending on the depth of the quench from the liquid into the glass: “simple” aging () applies for quenches close to the critical point of mode-coupling theory (MCT) and implies “subaging” ( with ) as a broad equilibration crossover for quenches to nearly arrested equilibrium states; “hyperaging” (or superaging, with ) emerges for quenches deep into the glass. The latter is cut off by non-mean-field fluctuations that we account for within a recent extension of MCT, the stochastic -relaxation theory (SBR). We exemplify the scaling laws with a schematic model that quantitatively fits simulation data.
中文翻译:
从结构玻璃的低老化到超老化
我们展示了玻璃成型体中老化和平衡动力学的非平衡标度定律,这些定律是通过将静态结构的弛豫方程与玻璃态动力学的平衡标度定律相结合而产生的。针对结构弛豫时间的演变预测了不同的缩放机制随着年龄(等待时间), 取决于从液体到玻璃的淬火深度:“简单”老化 () 适用于接近模式耦合理论 (MCT) 临界点的淬火并暗示“老化”(和) 作为淬火到几乎停滞的平衡状态的广泛平衡交叉;“过度老化”(或超级老化,和) 出现在玻璃深处淬火。后者被我们在 MCT 的最近扩展中解释的非平均场波动切断,随机-松弛理论(SBR)。我们用一个定量拟合模拟数据的示意图模型来举例说明比例定律。
更新日期:2022-11-30
中文翻译:
从结构玻璃的低老化到超老化
我们展示了玻璃成型体中老化和平衡动力学的非平衡标度定律,这些定律是通过将静态结构的弛豫方程与玻璃态动力学的平衡标度定律相结合而产生的。针对结构弛豫时间的演变预测了不同的缩放机制随着年龄(等待时间), 取决于从液体到玻璃的淬火深度:“简单”老化 () 适用于接近模式耦合理论 (MCT) 临界点的淬火并暗示“老化”(和) 作为淬火到几乎停滞的平衡状态的广泛平衡交叉;“过度老化”(或超级老化,和) 出现在玻璃深处淬火。后者被我们在 MCT 的最近扩展中解释的非平均场波动切断,随机-松弛理论(SBR)。我们用一个定量拟合模拟数据的示意图模型来举例说明比例定律。