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Crystal Chemistry and Physics of UCd11
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2022-11-29 , DOI: 10.1021/acs.inorgchem.2c01986
Nazar Zaremba 1 , Kristian Witthaut 1 , Yurii Prots 1 , Mitja Krnel 1 , Ulrich Burkhardt 1 , Zachary Fisk 2 , Yuri Grin 1 , Eteri Svanidze 1
Affiliation  

In the phase diagram U-Cd, only one compound has been identified so far─UCd11 (space group Pmm). Since the discovery of this material, the physical properties of UCd11 have attracted a considerable amount of attention. In particular, its complex magnetic phase diagram─as a result of tuning with magnetic field or pressure─is not well-understood. From a chemical perspective, a range of lattice parameter values have been reported, suggesting a possibility of a considerable homogeneity range, i.e., UCd11–x. In this work, we perform a simultaneous study of crystallographic features coupled with measurements of physical properties. This work sheds light on the delicate relationship between the intrinsic crystal chemistry and magnetic properties of UCd11.

中文翻译:

UCd11的晶体化学和物理

在U-Cd相图中,至今只鉴定出一种化合物─UCd 11 (空间群Pmm )。自从发现这种材料以来,UCd 11的物理性质引起了相当大的关注。特别是,它复杂的磁相图——由于磁场或压力调谐的结果——还没有被很好地理解。从化学角度来看,已报道了一系列晶格参数值,表明可能存在相当大的同质性范围,UCd 11–x. 在这项工作中,我们同时进行了晶体学特征研究和物理特性测量。这项工作揭示了 UCd 11的固有晶体化学和磁性之间的微妙关系。
更新日期:2022-11-29
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