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Aiming for dynamic behaviours of molecular metal chains
Dalton Transactions ( IF 3.5 ) Pub Date : 2022-11-29 , DOI: 10.1039/d2dt03442e
Tomoaki Tanase 1 , Kanako Nakamae 1 , Yasuyuki Ura 1 , Takayuki Nakajima 1
Affiliation  

The dynamical functions of molecular metal chains, that could be derived from unique physical and chemical properties coupled with self-assembly of metal chain components, have largely been unexplored, and this review paper focuses on the dynamic behaviours of Pd chains supported by linear tetraphosphines, meso- and rac-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 recently reported, and the current development on fine-tuning of metal chains by introducing heterometal atoms, i.e. heterometallic molecular metal chains, that are considered as promising dynamical components in the next generation.

中文翻译:

针对分子金属链的动态行为

分子金属链的动力学功能,可以从独特的物理和化学性质以及金属链组分的自组装中衍生出来,在很大程度上尚未被探索,这篇综述论文重点介绍了线性四膦支持的 Pd 链的动力学行为,meso - 和rac -Ph 2 PCH 2 P(Ph)CH 2 P(Ph)CH 2 PPh 2最近报道,通过引入异金属原子微调金属链,异金属分子金属链的当前进展,被认为是下一代有前途的动力组件。
更新日期:2022-11-29
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