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Ethylene as a synthon in carbonylative synthesis
Coordination Chemistry Reviews ( IF 20.6 ) Pub Date : 2022-11-28 , DOI: 10.1016/j.ccr.2022.214947
Jian-Xing Xu , Yang Yuan , Xiao-Feng Wu

We summarized and discussed the main achievements on transitional metal-catalyzed carbonylative transformations of ethylene in this review. Various bulk compounds and also fine chemicals, including propanol, alkyl propanoates, succinic diesters, and many multifunctionalized C3 compounds, can be produced by ethylene hydroformylation, hydroesterification, hydrocarboxylation, hydroaminocarbonylation, dicarbonylation, and multicomponent carbonylation reactions.



中文翻译:

乙烯作为羰基化合成中的合成子

在这篇综述中,我们总结和讨论了过渡金属催化乙烯羰基化转化的主要成果。各种大宗化合物和精细化学品,包括丙醇、丙酸烷基酯、琥珀酸二酯和许多多功能 C3 化合物,可以通过乙烯加氢甲酰化、加氢酯化、加氢羧化、加氢氨基羰基化、二羰基化和多组分羰基化反应生产。

更新日期:2022-11-28
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