Eosin Y mediated photo-catalytic C–H functionalization: C–C and C–S bond formation,Organic Chemistry Frontiers

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Eosin Y mediated photo-catalytic C–H functionalization: C–C and C–S bond formation
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2022-11-23 , DOI: 10.1039/d2qo01534j
Dinesh Singla ₁ , Vijay Luxami ₁ , Kamaldeep Paul ₁

Affiliation

C–C and C–S bonds are valuable in organic transformation for synthesizing various bioactive heterocycles. Owing to the increasing awareness of the step and atom economy of a reaction, organic chemists have promulgated the idea of sustainable and green chemistry for organic synthesis. Hence, photoredox catalysis using organic dyes as photocatalysts has attracted constant attention over the last decade. Herein, recent advances and developments (over the previous ten years, 2012–2022) in eosin Y mediated photoredox catalyzed synthetic organic transformations for C–C and C–S bond formation along with their different mechanistic pathways (such as SET, HAT, and energy transfer) are discussed. This review is classified into two major sections, (i) C–C and (ii) C–S bond formations, which are further sub-categorized into various types of functionalizations including arylation, alkenylation, annulation, thionation, and sulfonylation.

中文翻译：

曙红 Y 介导的光催化 C-H 功能化：C-C 和 C-S 键形成

C-C和C-S键在有机转化合成各种具有生物活性的杂环化合物中具有重要价值。由于对反应的步骤和原子经济性的认识不断提高，有机化学家提出了有机合成的可持续和绿色化学理念。因此，在过去十年中，使用有机染料作为光催化剂的光氧化还原催化一直受到关注。在此，曙红 Y 介导的光氧化还原催化 C-C 和 C-S 键形成的合成有机转化及其不同的机制途径（如 SET、HAT 和能量转移）进行了讨论。本综述分为两个主要部分，(i) C-C 和 (ii) C-S 键的形成，

更新日期：2022-11-23

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