iClick synthesis of network metallopolymers,Dalton Transactions

当前位置： X-MOL 学术 › Dalton Trans. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

iClick synthesis of network metallopolymers
Dalton Transactions ( IF 3.5 ) Pub Date : 2022-11-18 , DOI: 10.1039/d2dt01624a
Yu-Hsuan Shen ₁ , Ion Ghiviriga ₁ , Khalil A Abboud ₁ , Kirk S Schanze ₂ , Adam S Veige ₁

Affiliation

Described is an approach to preparing the first iClick network metallopolymers with porous properties. Treating digoldazido complex 2-AuN₃ with trigoldacetylide 3-AuPPh₃ or 3-AuPEt₃, trialkyne 3-H, tetragoldacetylide 4-AuPPh₃, or tetraalkyne 4-H in CH₂Cl₂ affords five iClick network metallopolymers 5-AuPPh₃, 5-AuPEt₃, 5-H, 6-AuPPh₃, and 6-H. Confirmation of the iClick network metallopolymers comes from FTIR, ¹³C solid-state cross-coupling magic angle spinning (CPMAS) NMR spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and nitrogen and CO₂ sorption analysis. Employing model complexes 7-AuPPh₃, 7-AuPEt₃, 7-H, 8-AuPPh₃, and 8-H provides structural insights due to the insolubility of iClick network metallopolymers.

中文翻译：

iClick合成网络金属聚合物

描述了一种制备第一个具有多孔特性的 iClick 网络金属聚合物的方法。用三金乙炔3-AuPPh ₃或3-AuPEt ₃、三炔3-H、四金乙炔4-AuPPh ₃或四炔4-H在 CH ₂ Cl ₂中处理二金叠氮基络合物2-AuN ₃得到五种 iClick 网络金属聚合物5-AuPPh ₃，5-AuPEt ₃、5-H、6-AuPPh ₃和6-H。iClick 网络金属聚合物的确认来自 FTIR，¹³ C 固态交叉耦合魔角旋转 (CPMAS) NMR 光谱、热重分析 (TGA)、差示扫描量热法 (DSC) 以及氮和 CO₂吸附分析。由于 iClick 网络金属聚合物的不溶性，使用模型复合物7-AuPPh ₃、 7-AuPEt ₃、 7-H、 8-AuPPh ₃和8-H提供了结构见解。

更新日期：2022-11-18

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11