A Platinum(II)-Based Molecular Cage with Aggregation-Induced Emission for Enzymatic Photocyclization of Alkynylaniline,Angewandte Chemie International Edition

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A Platinum(II)-Based Molecular Cage with Aggregation-Induced Emission for Enzymatic Photocyclization of Alkynylaniline
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-11-07 , DOI: 10.1002/anie.202214577
Zhong Wei ₁ , Xu Jing ₁ , Yang Yang ₁ , Jiayou Yuan ₁ , Mingxu Liu ₁ , Cheng He ₁ , Chunying Duan ₁

Affiliation

The photocyclization of alkynylanilines catalyzed by an aggregated Pt^II-based octahedral cage has been shown to mimic bio-enzyme catalysis by aggregated biological macromolecules. The aggregated supramolecular species exhibits a higher photocatalytic efficiency than dispersed metal-organic cages without aggregation.

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