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Bifunctional Europium for Operando Catalyst Thermometry in an Exothermic Chemical Reaction
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-11-03 , DOI: 10.1002/anie.202211991
Bas J P Terlingen 1 , Tjom Arens 1 , Thomas P van Swieten 1 , Freddy T Rabouw 1 , P Tim Prins 1 , Michiel M de Beer 2 , Andries Meijerink 1 , Mathieu P Ahr 3 , Eline M Hutter 1 , Coert E J van Lare 2 , Bert M Weckhuysen 1
Affiliation  

Temperature determines the reaction kinetics, thermodynamics and catalyst stability. However, very limited information is known about the local catalyst temperature. Here, operando thermometry over bifunctional Eu3+ is performed to study the interplay between reaction conditions and the catalyst temperature dynamics in the exothermic methane oxychlorination reaction.

中文翻译:

用于放热化学反应中原位催化剂测温的双功能铕

温度决定了反应动力学、热力学和催化剂稳定性。然而,关于局部催化剂温度的信息非常有限。在这里,对双功能 Eu 3+进行原位测温,以研究放热甲烷氧氯化反应中反应条件与催化剂温度动力学之间的相互作用。
更新日期:2022-11-03
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