当前位置: X-MOL 学术Theor. Exp. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Photocatalytic Evolution of Hydrogen from Alcohol–Aqueous Solutions using Nanocrystalline Carbon Nitride Modified with Magnesium Chloride Under the Visible Light Irradiation
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2022-10-08 , DOI: 10.1007/s11237-022-09736-3
G. Ya. Grodzyuk , K. V. Koryakina , V. V. Shvalagin , G. V. Korzhak , S. Ya. Kuchmiy

Samples of nanocrystalline graphite-like carbon nitride (CGCN) modified with magnesium chloride have been obtained. The synthesized Mg-CGCN samples have been characterized by UV and IR spectroscopies, X-ray diffraction, energy dispersive X-ray analysis, and scanning electron microscopy. It is found that Mg-CGCN exhibits 60% higher photocatalytic activity in the reaction of hydrogen evolution from aqueous ethanol solutions under visible light than undoped CGCN. This may be related to a change in electrophysical characteristics (potentials of allowed bands) resulting from the incorporation of Mg2+ ions into the CGCN structure, improved dissociation of photogenerated charges, and inhibition of their recombination.



中文翻译:

可见光照射下氯化镁改性纳米晶氮化碳从醇水溶液中光催化析氢

已经获得了用氯化镁改性的纳米晶类石墨氮化碳(CGCN)样品。合成的 Mg-CGCN 样品已通过紫外和红外光谱、X 射线衍射、能量色散 X 射线分析和扫描电子显微镜进行了表征。研究发现,Mg-CGCN 在可见光下乙醇水溶液析氢反应中的光催化活性比未掺杂的 CGCN 高 60%。这可能与将 Mg 2+离子结合到 CGCN 结构中、改善光生电荷的解离和抑制它们的复合而导致的电物理特性(允许带的电位)的变化有关。

更新日期:2022-10-09
down
wechat
bug