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Enantioselective Selenol-ene Using Rh-Hydride Catalysis
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2022-09-26 , DOI: 10.1021/jacs.2c08475
Hannah S Slocumb 1 , Shaozhen Nie 1 , Vy M Dong 1 , Xiao-Hui Yang 2
Affiliation  

This study showcases the first enantioselective hydroselenation of styrenes. Organoselenium building blocks are accessed with selectivity for the branched isomer. Through a Rh-hydride pathway, C–Se bonds can be forged with excellent regio- and enantiocontrol.

中文翻译:

使用 Rh-Hydride 催化的对映选择性 Selenol-ene

这项研究展示了苯乙烯的第一次对映选择性氢化硒化。有机硒结构单元对支链异构体具有选择性。通过Rh-氢化物途径,可以形成具有出色区域和对映控制的C-Se键。
更新日期:2022-09-26
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