Phosphazenes, one of the most important classes of organophosphorus compounds containing phosphorus (V) with double bonds between P and N, can be cyclic molecules or high molecular weight polymers that play an important and dominant role in advanced inorganic materials. Phosphazenes have been the subject of many studies over the past two decades as an excellent synthetic platform for the development of fluorescent materials. This study is conducted to evaluate the contribution of phosphazene chemistry to the preparation of fluorescent materials and to emphasize its importance in development of sophisticated materials. This review provides detailed information about the latest developments in the field of cyclic-, dendrimeric- and polymeric phosphazenes based fluorescent materials and their application examples of sensors (fluorescent and electrochemical) and optoelectronic devices (OLED, OFET and electrochromic devices). The future perspective of fluorescence materials based on phosphazenes is also discussed.

磷腈是一类最重要的含磷（V）的有机磷化合物，在P和N之间具有双键，可以是环状分子或高分子量聚合物，在先进的无机材料中起重要和主导作用。在过去的二十年中，磷腈作为开发荧光材料的绝佳合成平台一直是许多研究的主题。本研究旨在评估磷腈化学对制备荧光材料的贡献，并强调其在开发复杂材料中的重要性。这篇评论提供了有关循环领域最新发展的详细信息，基于树枝状和聚合磷腈的荧光材料及其在传感器（荧光和电化学）和光电器件（OLED、OFET 和电致变色器件）中的应用实例。还讨论了基于磷腈的荧光材料的未来前景。