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Ion-adsorption type rare earth tailings for preparation of alkali-based geopolymer with capacity for heavy metals immobilization
Cement and Concrete Composites ( IF 10.8 ) Pub Date : 2022-09-15 , DOI: 10.1016/j.cemconcomp.2022.104768
Baifa Zhang , Ting Yu , Liangliang Deng , Yun Li , Haozhe Guo , Junming Zhou , Lijuan Li , Yuan Peng

Ion-adsorption type rare earth tailings (RET), a type of solid waste that contains clay minerals, were used as a starting material to prepare alkali-based geopolymer. The effects on the compressive strength of RET-based geopolymer, including the modulus and concentration of the alkaline activator, curing temperature, and liquid/solid ratio, were investigated. Pb2+ and Cd2+ were added during the preparation of the RET-based geopolymer for evaluating the immobilization capacity of heavy metals in the as-obtained geopolymer. The results showed that geopolymer with a compact and dense microstructure was obtained through the optimization of the above factors, with the highest compressive strength being 28.5 MPa. The leaching test indicated that the RET-based geopolymer possessed a desirable capacity for immobilizing heavy metals, where the immobilization efficiency of Pb2+ was above 99% and that of Cd2+ ranged from 92% to 96%. Heavy metals were immobilized in the RET-based geopolymer matrix through the formation of chemical bonds (T (Si, Al)–O–M (Pb, Cd)) or through an electrostatic attraction between the metal cations and negatively charged [AlO4].



中文翻译:

离子吸附型稀土尾矿制备具有重金属固定能力的碱基地质聚合物

离子吸附型稀土尾矿(RET)是一种含有粘土矿物的固体废物,被用作制备碱基地质聚合物的起始原料。研究了对RET基地质聚合物抗压强度的影响,包括碱性活化剂的模量和浓度、固化温度和液固比。Pb2+和 Cd2+在 RET 基地质聚合物的制备过程中添加,用于评估固定化获得的地质聚合物中重金属的容量。结果表明,通过对上述因素的优化,得到了微观结构致密、致密的地质聚合物,最高抗压强度为28.5 MPa。浸出试验表明,RET基地质聚合物具有较好的重金属固定化能力,Pb 2+固定化率在99%以上,Cd 2+固定化率在92%~96%之间。重金属通过化学键 (T (Si, Al)–O–M (Pb, Cd)) 的形成或金属阳离子与带负电荷的 [AlO 4 ]之间的静电吸引力固定在基于 RET 的地质聚合物基质中-

更新日期:2022-09-20
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