Regioselective Access to Vicinal Diamines by Metal-Free Photosensitized Amidylimination of Alkenes with Oxime Esters,Angewandte Chemie International Edition

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Regioselective Access to Vicinal Diamines by Metal-Free Photosensitized Amidylimination of Alkenes with Oxime Esters
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-09 , DOI: 10.1002/anie.202212292
Yu Zheng ₁ , Zhu-Jun Wang ₁ , Zhi-Peng Ye ₁ , Kai Tang ₁ , Zhen-Zhen Xie ₁ , Jun-An Xiao ₂ , Hao-Yue Xiang _{1,

3} , Kai Chen ₁ , Xiao-Qing Chen ₁ , Hua Yang ₁

Affiliation

A metal-free, photosensitized regioselective diamination of alkene is reported. The keys to this advance are: 1) rational design of bifunctional diamination reagent, 2) simultaneous generation of long-lived iminyl radical and transient amidyl radical with significantly differed reactivities, and 3) involvement of photoinduced energy transfer reaction mode.

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