Salting-Out Aldehyde from the Electrooxidation of Alcohols with 100 % Selectivity,Angewandte Chemie International Edition

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Salting-Out Aldehyde from the Electrooxidation of Alcohols with 100 % Selectivity
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-08 , DOI: 10.1002/anie.202210123
Leitao Xu ₁ , Zhifeng Huang ₁ , Ming Yang ₁ , Jingcheng Wu ₁ , Wei Chen ₁ , Yandong Wu ₁ , Yuping Pan ₁ , Yuxuan Lu ₁ , Yuqin Zou ₁ , Shuangyin Wang ₁

Affiliation

Selective electrocatalytic oxidation of alcohols to aldehydes has significant challenges, for example, it cannot realize the preparation of aldehydes selectively in alkaline aqueous solutions. By tuning the local microenvironment over the electrocatalyst, and thus selectively salting-out the aldehyde at the gas|electrolyte interface, the electrocatalytic synthesis of aldehydes was achieved in an efficient and green way.

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