High-Capacity Splitting of Mono- and Dibranched Hexane Isomers by a Robust Zinc-Based Metal–Organic Framework,Angewandte Chemie International Edition

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High-Capacity Splitting of Mono- and Dibranched Hexane Isomers by a Robust Zinc-Based Metal–Organic Framework
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-05 , DOI: 10.1002/anie.202211359
Liang Yu _{1,

2} , Saif Ullah ₃ , Hao Wang ₁ , Qibin Xia ₂ , Timo Thonhauser ₃ , Jing Li _{1,

4}

Affiliation

A microporous Zn-based metal–organic framework material with high surface area and optimal pore aperture has been used for the discrimination of alkane isomers. It adsorbs linear and monobranched alkanes but fully excludes their dibranched isomer, with high capacities and selectivities, outperforming other splitters for alkane isomers.

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