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Surface Diffusion Aided by a Chirality Change of Self-Assembled Oligomers under 2D Confinement
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-02 , DOI: 10.1002/anie.202212245
Abhijit Bera 1 , Stefan Henkel 2 , Joel Mieres-Perez 3 , Yetsedaw Andargie Tsegaw 2 , Elsa Sanchez-Garcia 3 , Wolfram Sander 2 , Karina Morgenstern 1
Affiliation  

We demonstrate a new functional molecular system with a combination of several advanced features, including a self-assembled oligomer, surface chirality, chirality switching, and finally their motion on the surface. Our results suggest that nonchiral molecules may be designed to induce switchable enantiomeric surface assemblies, relevant for heterogeneous catalysts.

中文翻译:


二维限制下自组装低聚物的手性变化辅助的表面扩散



我们展示了一种新的功能分子系统,它结合了多种先进功能,包括自组装低聚物、表面手性、手性转换以及最终它们在表面上的运动。我们的结果表明,非手性分子可以被设计来诱导与多相催化剂相关的可转换的对映体表面组装。
更新日期:2022-09-02
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