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Review of molecular imprinting polymer: basic characteristics and removal of phenolic contaminants based on the functionalized cyclodextrin monomer
Journal of Chemical Technology and Biotechnology ( IF 2.8 ) Pub Date : 2022-08-20 , DOI: 10.1002/jctb.7215
Syed Fariq Fathullah Syed Yaacob 1 , Mamman Suwaibatu 1 , Raja Zalinda Raja Jamil 1 , Nur Nadhirah Mohamed Zain 2 , Muggundha Raoov 3 , Faiz Bukhari Mohd Suah 1
Affiliation  

Cyclodextrins (CDs) are formed of starch molecules that are linked together in a cyclic ring. They are composed of five or more (1, 4) connected D-glucopyranoside units. CDs have toroidal, hollow truncated cone structures with exterior hydrophilic edges and internal hydrophobic cavities. The numerous hydroxyl groups available in cyclodextrins are active sites capable of forming various sorts of connections. They can be cross-linked or derived to generate monomers able to form branching or linear networks. Furthermore, they can form inclusion complexes with a variety of guest molecules, including organic and inorganic molecules, thus changing their physicochemical properties, The modification of the imprinting method could produce molecularly imprinted polymers that are stable, dependable, long-lasting, selective, and cost-effective. As a result, molecularly imprinted polymers are becoming increasingly popular in chemical separation and analysis. As found in previous studies, the monomers of cyclodextrins used in molecular imprinting have a higher binding impact on target molecules. The purpose of this study is to highlight the application of imprinting technology utilizing cyclodextrins as a valuable functional monomer in the remediation of phenolic compounds by examining and assessing relevant works published in the literature. © 2022 Society of Chemical Industry (SCI).

中文翻译:

分子印迹聚合物综述:基于功能化环糊精单体的酚类污染物的基本特性和去除

环糊精 (CD) 由在环状环中连接在一起的淀粉分子形成。它们由五个或更多 (1, 4) 个相连的 D-吡喃葡萄糖苷单元组成。CD 具有环形、空心截锥结构,具有外部亲水边缘和内部疏水腔。环糊精中存在的大量羟基是能够形成各种连接的活性位点。它们可以交联或衍生以生成能够形成分支或线性网络的单体。此外,它们还可以与多种客体分子,包括有机分子和无机分子形成包合物,从而改变它们的理化性质,改进印迹方法可以生产出稳定、可靠、持久、选择性好、性价比高。因此,分子印迹聚合物在化学分离和分析中越来越受欢迎。正如在之前的研究中发现的那样,用于分子印迹的环糊精单体对目标分子具有更高的结合作用。本研究的目的是通过检查和评估文献中发表的相关著作,突出利用环糊精作为有价值的功能单体的印迹技术在修复酚类化合物中的应用。© 2022 化学工业协会 (SCI)。本研究的目的是通过检查和评估文献中发表的相关著作,突出利用环糊精作为有价值的功能单体的印迹技术在修复酚类化合物中的应用。© 2022 化学工业协会 (SCI)。本研究的目的是通过检查和评估文献中发表的相关著作,突出利用环糊精作为有价值的功能单体的印迹技术在修复酚类化合物中的应用。© 2022 化学工业协会 (SCI)。
更新日期:2022-08-20
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