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Stabilization technology and corrosion mechanism of rust layer on Q370 weathering steel surface
Journal of Iron and Steel Research International ( IF 3.1 ) Pub Date : 2022-08-13 , DOI: 10.1007/s42243-022-00819-y
Shao-zheng Ma , Li-juan Sun , Hu-yuan Sun , Hong-bin Sun , Jin-feng Jiang , Yi-xin Yin , Shu-feng Qu , Zhen-hua Liu , Shao-xia Xu

A newly developed rust layer on Q370qENH weathering steel (sample C) was studied under dry–wet cycle test of 3.5 wt.% NaCl solution and salt spray test, compared with the bare weathering steel (sample A) and the weathering steel with additive contents (CuSO4 0.2, FeSO4 0.1, NaHSO3 0.02, NaCl 0.02, Na2HPO4 0.01, and water balance, in mass%, termed as sample B). Corrosion mechanism of Q370qENH weathering steel after different surface treatments was investigated by means of surface potential scanning, mass change, polarization curve, and X-ray diffraction. The results of X-ray diffraction indicate that rust of bare weathering steel has rare Fe3O4, and a dense oxide layer mainly composed of Fe3O4 is formed on rust of both sample B and sample C. The surface potential of sample A gradually increases to − 0.2 V in the dry–wet cycle test, while the surface potential of sample A maintains at about − 0.6 V in the salt spray test. The surface potential of sample B and sample C is higher than that of sample A in the early stage and remains stable during the short-term accelerated corrosion test. Moreover, the mass change of sample C gradually stabilizes with time in the dry–wet cycle and salt spray test. The corrosion current of the sample A is lower than that of sample C in the initial stage of short-term accelerated corrosion test. However, the corrosion current of sample C is smaller than that of the sample A in the experiment. The main components of the deep rust of sample A are γ-FeOOH and α-FeOOH, while those of the deep rust of sample B and sample C are Fe3O4.



中文翻译:

Q370耐候钢表面锈层稳定化技术及腐蚀机理

通过 3.5 wt.% NaCl 溶液的干湿循环试验和盐雾试验,研究了 Q370qENH 耐候钢(样品 C)上新开发的锈层,并与裸耐候钢(样品 A)和添加含量的耐候钢进行了比较(CuSO 4 0.2、FeSO 4 0.1、NaHSO 3 0.02、NaCl 0.02、Na 2 HPO 4 0.01 和水平衡,以质量%计,称为样品 B)。通过表面电位扫描、质量变化、极化曲线、X射线衍射等方法研究了Q370qENH耐候钢不同表面处理后的腐蚀机理。X射线衍射结果表明,裸露的耐候钢锈中含有稀有的Fe 3 O 4, 以及主要由 Fe 3 O 4组成的致密氧化层样品 B 和样品 C 都生锈。样品 A 的表面电位在干湿循环试验中逐渐升高到 - 0.2 V,而样品 A 的表面电位在盐雾试验中保持在 - 0.6 V 左右. 样品 B 和样品 C 的表面电位在早期高于样品 A,在短期加速腐蚀试验中保持稳定。此外,在干湿循环和盐雾试验中,样品 C 的质量变化随时间逐渐稳定。在短期加速腐蚀试验初期,样品A的腐蚀电流低于样品C。但实验中样品C的腐蚀电流小于样品A的腐蚀电流。样品A深锈的主要成分是γ-FeOOH和α-FeO​​OH,3 O 4

更新日期:2022-08-13
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