Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2022-08-11 , DOI: 10.1016/j.jallcom.2022.166745 Wenjie Zhao , Yujie Zhang , Haomiao Li , Kangli Wang , Kai Jiang
Molten salt synthesis is a facile, extensible and effective way to obtain specific electrode materials with in situ carbon coating. Herein, a carbon coating Mo6S8 compounds were synthesized based on molten KCl medium, and the excellent electrochemical Mg-storage performance were demonstrated in rechargeable Mg ion batteries. Benefiting from the in situ carbon coating, the as-synthesized Mo6S8@C delivers a high reversible capacity of 90 mAh g–1 and a superior rate performance. Further mechanism investigation via kinetics testing, ex situ XRD and XPS demonstrate that the carbon coating layer on the surface of Mo6S8 could accelerate the electron/ion transport and improve the rate performance and stability of the electrodes. This work provides a possible way to large-scale fabrication of the carbon coating Mo6S8 and lays a foundation for the practical applications of Mg ion batteries.
中文翻译:
在熔盐中大规模制造碳涂层 Chevrel 相:对高性能镁离子电池正极的启示
熔盐合成是一种简便、可扩展且有效的获得具有原位碳涂层的特定电极材料的方法。在此,基于熔融 KCl 介质合成了碳涂层 Mo 6 S 8化合物,并在可充电镁离子电池中展示了优异的电化学储镁性能。得益于原位碳涂层,合成后的 Mo 6 S 8 @C 具有 90 mAh g -1的高可逆容量和卓越的倍率性能。通过动力学测试、非原位 XRD 和 XPS 的进一步机理研究表明,Mo 6 S 8表面的碳涂层可以加速电子/离子传输,提高电极的倍率性能和稳定性。该工作为大规模制备碳涂层Mo 6 S 8提供了可能的途径,为镁离子电池的实际应用奠定了基础。