Iron-catalyzed deconstructive alkylation through chlorine radical induced C–C single bond cleavage under visible light,Chemical Communications

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Iron-catalyzed deconstructive alkylation through chlorine radical induced C–C single bond cleavage under visible light
Chemical Communications ( IF 4.3 ) Pub Date : 2022-08-12 , DOI: 10.1039/d2cc03896j
Qiang Wu ₁ , Wei Liu ₁ , Miao Wang ₁ , Yahao Huang ₁ , Peng Hu ₁

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Selective C–C single bond cleavage of simple compounds is a highly challenging and desired process. Herein, a chlorine radical-induced deconstructive C–C bond alkylation with alcohols and alkenes catalyzed by iron salts was reported for the first time. Readily available alcohols and various electron-deficient alkenes were tolerated. Late-stage and large-scale reactions proceed smoothly. This catalyst system shows potential for diversified deconstructive functionalization of simple C–C bonds.

中文翻译：

可见光下氯自由基诱导的 C-C 单键断裂铁催化的解构烷基化

简单化合物的选择性 C-C 单键断裂是一个极具挑战性和理想的过程。在此，首次报道了氯自由基诱导的由铁盐催化的醇和烯烃的解构C-C键烷基化反应。容易获得的醇和各种缺电子烯烃是可以耐受的。后期和大规模反应顺利进行。该催化剂体系显示出对简单 C-C 键进行多样化解构功能化的潜力。

更新日期：2022-08-12

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