当前位置: X-MOL 学术J. Clean. Prod. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Activate nutrients access to plants as multiphase slow-release fertilizers by sintering reaction in K2O–MgO–Al2O3–SiO2 system using K-feldspar as a major source
Journal of Cleaner Production ( IF 9.7 ) Pub Date : 2022-08-10 , DOI: 10.1016/j.jclepro.2022.133511
Longfeng Tao , Ling Guo , Changjiang Liu , Xi Ma , Hongwen Ma

The sintering reactions in K2O–MgO–Al2O3–SiO2 system using K-feldspar, magnesite, and potassium carbonate as the starting materials were studied to prepare potassium magnesium silicates and potassium aluminosilicates as multiphase slow-release fertilizers (SRFs). Effects of sintering temperature (850–1250 °C), time (1–5 h), and addition of K2CO3 (100 %–130%) on the reaction extents as well as the types of final products were investigated. Results showed that the multi-phases of K1.14Mg0.57Si1.43O4 and KAlSiO4 were prepared as stable products under the concerned conditions of 1050 °C for 2h, and K2MgSiO4 was obtained instead of K1.14Mg0.57Si1.43O4 under the situation of adding excessive K2CO3. Sintering experiments of five raw mixtures were designed to discuss reaction mechanism by comparing the Al-phases in final products. The results indicated that Al2O3 component favored to persist as potassium aluminosilicates (KAlSiO4 or KAlSi2O6), and three multiphase compounds, KAlSiO4 + K1.14Mg0.57Si1.43O4, KAlSiO4 + K2MgSi3O8, and KAlSi2O6 + K2MgSi3O8 were successfully prepared at optimal conditions and subsequently characterized. Solubility tests of sintered samples in water, 20 g/L critic acid solution, and 0.5 mol/L hydrochloric acid solution showed that the three samples exhibited increasing solubility orderly with consistent component soluble sequence of MgO > K2O ≥ Al2O3 > SiO2 in different solutions. K1.14Mg0.57Si1.43O4 is found to perform the best soluble behavior, while KAlSi2O6 shows a less soluble behavior. Present work proposed considerable approaches to make the inert elements in minerals (K-feldspar and magnesite) and the active element (K) in potassium carbonate accessible for plants in a slow-release route.



中文翻译:

通过以钾长石为主要来源的 K2O–MgO–Al2O3–SiO2 体系中的烧结反应,激活植物作为多相缓释肥料的养分获取途径

以钾长石、菱镁矿和碳酸钾为原料,研究了K 2 O–MgO–Al 2 O 3 –SiO 2体系中的烧结反应,制备了硅酸镁钾和铝硅酸钾作为多相缓释肥料(SRFs) 。 )。研究了烧结温度(850–1250 °C)、时间(1–5 h)和K 2 CO 3添加量(100%–130%)对反应程度和最终产物类型的影响。结果表明,K 1.14 Mg 0.57 Si 1.43 O 4和 KAlSiO 的多相在1050℃反应2h的相关条件下制备出稳定的产物4,在加入过量K 2 CO 3的情况下得到K 2 MgSiO 4代替K 1.14 Mg 0.57 Si 1.43 O 4。设计了五种原料混合物的烧结实验,通过比较最终产品中的铝相来讨论反应机理。结果表明,Al 2 O 3组分有利于以铝硅酸钾(KAlSiO 4或 KAlSi 2 O 6)和三种多相化合物 KAlSiO 4的形式存在。 + K 1.14 Mg 0.57 Si 1.43 O 4、KAlSiO 4  + K 2 MgSi 3 O 8和KAlSi 2 O 6  + K 2 MgSi 3 O 8在最佳条件下成功制备并随后进行了表征。烧结样品在水中、20 g/L 临界酸溶液和 0​​.5 mol/L 盐酸溶液中的溶解度测试表明,三种样品的溶解度依次递增,组分溶解顺序一致,MgO > K 2 O ≥ Al 2 O 3  >二氧化硅_在不同的解决方案中。发现K 1.14 Mg 0.57 Si 1.43 O 4表现出最好的可溶性,而KAlSi 2 O 6表现出较不溶性。目前的工作提出了相当多的方法,使矿物(钾长石和菱镁矿)中的惰性元素和碳酸钾中的活性元素 (K) 可通过缓释途径被植物吸收。

更新日期:2022-08-13
down
wechat
bug