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Isolating elusive ‘Al(μ-O)M’ intermediates in CO2 reduction by bimetallic Al–M complexes (M = Zn, Mg)
Chemical Communications ( IF 4.9 ) Pub Date : 2022-08-11 , DOI: 10.1039/d2cc04028j
Matthew J Evans 1 , George H Iliffe 1 , Samuel E Neale 2 , Claire L McMullin 2 , J Robin Fulton 1 , Mathew D Anker 1 , Martyn P Coles 1
Affiliation  

The reaction of compounds containing Al–Mg and Al–Zn bonds with N2O enabled isolation of the corresponding Al(μ-O)M complexes. Electronic structure analysis identified largely ionic Al–O and O–M bonds, featuring an anionic μ-oxo centre. Reaction with CO2 confirmed that these species correspond to the proposed intermediates in the formation of μ-carbonate compounds.

中文翻译:

通过双金属 Al-M 配合物 (M = Zn, Mg) 在 CO2 还原中分离难以捉摸的“Al(μ-O)M”中间体

含有 Al-Mg 和 Al-Zn 键的化合物与 N 2 O 的反应能够分离相应的 Al(μ-O) M配合物。电子结构分析主要识别离子 Al-O 和 O- M键,具有阴离子 μ-氧中心。与 CO 2的反应证实这些物质对应于所提出的形成 μ-碳酸盐化合物的中间体。
更新日期:2022-08-11
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