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Catalytic conversion of CO2 by supported ionic liquid prepared with supercritical fluid deposition in a continuous fixed-bed reactor
Journal of CO2 Utilization ( IF 7.7 ) Pub Date : 2022-08-09 , DOI: 10.1016/j.jcou.2022.102168
Xintong Li , Jianfei Sun , Mantong Xue , Jianzhong Yin

The capture and fixation of CO2 can effectively alleviate greenhouse effect. Propylene carbonate is a highly efficient solvent, which can be used as an excellent medium for lithium battery. It is of great significance to convert CO2 into propylene carbonate. In this paper, ionic liquid BMImBr was immobilized into the pores of SBA-15 by supercritical deposition, and BMImBr@SBA-15 was obtained for catalytic conversion of CO2. The catalytic properties of BMImBr and BMImBr@SBA-15 were investigated by batch method. Then the catalytic performance of supported catalyst BMImBr@SBA-15 was investigated by continuous method, which was carried out in a fixed-bed reactor. The continuous experiments controlled the CO2 pressure change (0.5–2.0 MPa) when the inlet liquid flow rate was 0.02 mL/min and 0.04 mL/min. Under the conditions of 0.04 mL/min and 1.0 MPa, the yield was the highest (66.14 %). In this paper, through the calculation of the reaction rate constant, it can be concluded that the continuous method can avoid the repeated packing of the catalyst and obtain a higher yield in a short time. It has a broad prospect of industrialization.



中文翻译:

连续固定床反应器中超临界流体沉积制备负载型离子液体催化转化CO2

CO 2的捕获和固定可以有效缓解温室效应。碳酸丙烯酯是一种高效溶剂,可用作锂电池的优良介质。将CO 2转化为碳酸亚丙酯具有重要意义。本文通过超临界沉积将离子液体BMImBr固定在SBA-15的孔隙中,获得了用于催化CO 2转化的BMImBr@SBA-15 。采用间歇法研究了BMImBr和BMImBr@SBA-15的催化性能。然后在固定床反应器中采用连续法研究了负载型催化剂BMImBr@SBA-15的催化性能。连续实验控制CO 2入口液体流速为 0.02 mL/min 和 0.04 mL/min 时的压力变化(0.5-2.0 MPa)。在 0.04 mL/min 和 1.0 MPa 的条件下,产率最高(66.14 %)。本文通过对反应速率常数的计算得出,连续法可以避免催化剂的重复装填,在短时间内获得较高的收率。具有广阔的产业化前景。

更新日期:2022-08-09
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