In-depth investigation of cooperative [M]-/Organo-catalytic systems in aerobic Si−H− to Si−OH-group oxidation showed the efficiency of the two “complementary” catalytic systems, based on earth-abundant [M]-catalysts and inexpensive commercially available organic catalysts. [Co]/NHSI (A) system made it possible to oxidize a wide range of monomers but failed in the case of oligomeric and polymeric substrates. This problem was solved by application of [Cu]/NHPI (B) system.

中文翻译：

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多种 Si−H 试剂有氧氧化为 Si−OH 产物的互补协同催化系统：从单体到低聚物和聚合物

对好氧 Si-H- 到 Si-OH 基团氧化中协同 [M]-/有机催化系统的深入研究表明，基于地球丰富的 [M]-催化剂，这两种“互补”催化系统的效率和廉价的市售有机催化剂。[Co]/NHSI (A) 系统可以氧化多种单体，但在低聚和聚合物基材的情况下却失败了。通过应用[Cu]/NHPI (B) 体系解决了这个问题。