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Macro-controlling of the element distribution to prepare high-performance sintered (Nd, Dy)-Fe-B composite magnets
Intermetallics ( IF 4.3 ) Pub Date : 2022-08-05 , DOI: 10.1016/j.intermet.2022.107679
Yuan Qin , Weiqiang Liu , ZhuBai Li , Hao Chen , HaiHui Wu , Zizhen Guo , TianYuan Yang , Yuqing Li , Ming Yue

Two magnets prepared by dual-main-phase (Nd13Fe81B6 and Dy21Fe73B6) and single-main-phase (Nd13Fe81B6 with DyHx doping) approaches. The content of the Dy element in the composite magnet with dual-main-phase structure (6.75 wt%) is lower than that of the magnet with single-main-phase structure (7 wt%). But the dual-main-phase magnet's coercivity, remanence, and the magnetic energy product are 5.08 kOe, 0.36 kG, and 2.99 MGOe, higher than those of the single-main-phase magnet. In the dual-main-phase magnet, the diffusion of Nd and Dy elements is more prominent. Part Dy element replaces the Nd element to form (Nd, Dy)2Fe14B phase, and the remaining Dy element exists in the form of Dy2Fe14B phase, which improves the comprehensive magnetic performance of the magnet. As a result, Dy element in the dual-main-phase magnet is fully utilized. In the single-main-phase magnet, the Dy element replaces the Nd element to form the (Nd, Dy)2Fe14B phase. However, the remaining non-magnetic Dy element from DyHx concentrates in the grain boundary, it reduces the magnetic properties of magnets and leads to the waste of Dy elements. The results show that the dual-main-phase structure can control the diffusion of Nd and Dy elements, optimize the distribution of Dy elements, effectively increase the utilization rate of Dy elements and improve the comprehensive magnetic properties of sintered magnets.



中文翻译:

宏观调控元素分布以制备高性能烧结 (Nd, Dy)-Fe-B 复合磁体

由双主相(Nd 13 Fe 81 B 6和 Dy 21 Fe 73 B 6)和单主相(Nd 13 Fe 81 B 6和 DyH x )制备的两个磁体兴奋剂)方法。双主相结构复合磁体中Dy元素的含量(6.75 wt%)低于单主相结构磁体(7 wt%)。但双主相磁体的矫顽力、剩磁和磁能积分别为5.08 kOe、0.36 kG和2.99 MGOe,高于单主相磁体。在双主相磁体中,Nd和Dy元素的扩散更为突出。部分Dy元素代替Nd元素形成(Nd, Dy) 2 Fe 14 B相,剩余的Dy元素以Dy 2 Fe 14的形式存在B相,提高了磁体的综合磁性能。结果,双主相磁体中的Dy元素被充分利用。在单主相磁铁中,Dy元素代替Nd元素形成(Nd,Dy) 2 Fe 14 B相。然而,DyH x中剩余的非磁性Dy元素集中在晶界,降低了磁体的磁性,导致Dy元素的浪费。结果表明,双主相结构可以控制Nd和Dy元素的扩散,优化Dy元素的分布,有效提高Dy元素的利用率,提高烧结磁体的综合磁性能。

更新日期:2022-08-05
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