(Chemo)biocatalytic Upgrading of Biobased Furanic Platforms to Chemicals, Fuels, and Materials: A Comprehensive Review,ACS Catalysis

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(Chemo)biocatalytic Upgrading of Biobased Furanic Platforms to Chemicals, Fuels, and Materials: A Comprehensive Review
ACS Catalysis ( IF 11.3 ) Pub Date : 2022-08-04 , DOI: 10.1021/acscatal.2c02912
Ning Li ₁ , Min-Hua Zong ₁

Affiliation

Biobased furans, such as furfural, 5-hydroxymethylfurfural, and 2,5-furandicarboxylic acid, are recognized as the top-value platform chemicals in the valorization of biomass to chemicals, fuels, and materials. Biocatalysis has emerged as a promising technique in the chemical and pharmaceutical industries because of exquisite selectivity, mild reaction conditions, environmental friendliness, etc. In this comprehensive review, we summarize the recent advances in (chemo)biocatalytic conversion of biobased furans, based on the reaction types including oxidation, reduction, C–C and C–N bonds formation, esterification, and amidation. Particularly, the biocatalysts and their catalytic mechanisms/pathways are critically discussed to allow the rational design and construction of efficient enzymes/multienzyme systems/chemobiocatalytic systems. Besides, various biocatalyst engineering and reaction engineering strategies are highlighted to intensify the processes. Future research directions are proposed to expand the chemical space of furans as well as to improve the commercial acceptance of biocatalytic processes.

中文翻译：

生物基呋喃平台向化学品、燃料和材料的（化学）生物催化升级：综合综述

生物基呋喃，如糠醛、5-羟甲基糠醛和 2,5-呋喃二甲酸，被认为是在将生物质转化为化学品、燃料和材料方面价值最高的平台化学品。生物催化因其选择性精细、反应条件温和、环境友好等优点，已成为化学和制药行业的一项有前途的技术。在这篇综合综述中，我们总结了生物基呋喃（化学）生物催化转化的最新进展，基于反应类型包括氧化、还原、C-C 和 C-N 键的形成、酯化和酰胺化。特别是，对生物催化剂及其催化机制/途径进行了批判性讨论，以允许合理设计和构建有效的酶/多酶系统/化学生物催化系统。除了，强调了各种生物催化剂工程和反应工程策略以加强该过程。提出了未来的研究方向，以扩大呋喃的化学空间以及提高生物催化过程的商业接受度。

更新日期：2022-08-04

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