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The early-stage design of plasma for the conversion of CO2 to chemicals: A prospective techno-economic assessment
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2022-08-03 , DOI: 10.1016/j.jcou.2022.102156
Hanne Lamberts-Van Assche , Gwenny Thomassen , Tine Compernolle

The persistent increase in CO2 emissions and the continued depletion of fossil resources are two major challenges of the 21st century. These challenges can be tackled with Carbon Capture and Utilization (CCU), fby capturing and using CO2 as a valuable feedstock. Plasma presents a reactive environment to convert the CO2 molecule efficiently into higher-value chemicals and is a promising CCU technology in an early development stage. This study translates the technical performance of the plasma, as observed in the laboratory, into economic cashflows on a pilot plant level. In this techno-economic assessment, the influence of three features of the plasma is analyzed: the type of feed, the space time and the type of packing material. The economic feasibility of the different plasma configurations for the conversion of CO2 and CH4 into higher-value chemicals is assessed by calculating the Net Present Value (NPV). This allows the identification of the major cost items and the prioritization of future R&D steps. Negative NPVs are observed for all configurations, due to high electricity expenses, high capital investments and insufficient revenues. Based on the NPV, the most promising reactor configuration is the unpacked reactor, supplied with pure CO2 in a short space time. However, to target higher-value chemicals and raise revenues, the presence of packing materials and a mixed feed of CO2 and CH4 is crucial. Indeed, the highest revenues are observed for the reactor filled with packing, supplied with CO2 & CH4 and at longer space time. To move forward, the right type of packing material should be found, enabling the targeted production of higher-value chemicals with higher conversion rates in a shorter space time.



中文翻译:

用于将二氧化碳转化为化学品的等离子体的早期设计:一项前瞻性技术经济评估

CO 2排放量的持续增加和化石资源的持续枯竭是 21 世纪的两大挑战。这些挑战可以通过碳捕获和利用 (CCU) 解决,即捕获和使用 CO 2作为有价值的原料。等离子体提供了一种反应环境来转化 CO 2分子有效地转化为更高价值的化学品,是一种处于早期开发阶段的有前途的 CCU 技术。本研究将实验室观察到的等离子体技术性能转化为中试工厂水平的经济现金流。在这项技术经济评估中,分析了等离子体的三个特征的影响:进料类型、时空和包装材料类型。不同等离子体配置转化 CO 2和 CH 4的经济可行性通过计算净现值 (NPV) 来评估高价值化学品。这允许识别主要成本项目和未来研发步骤的优先级。由于高电费、高资本投资和收入不足,所有配置都观察到负 NPV。基于 NPV,最有希望的反应器配置是无填料反应器,在短时间内供应纯 CO 2 。然而,为了瞄准更高价值的化学品并增加收入,包装材料的存在以及 CO 2和 CH 4的混合进料至关重要。实际上,在填充有 CO 2和 CH 4的填料的反应器中观察到最高的收入并且在更长的时空中。为了向前迈进,应该找到正确类型的包装材料,从而能够在更短的空间内有针对性地生产具有更高转化率的更高价值化学品。

更新日期:2022-08-03
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