Ring-opening of non-activated aziridines with [11C]CO2 via novel ionic liquids,RSC Advances

当前位置： X-MOL 学术 › RSC Adv. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Ring-opening of non-activated aziridines with [11C]CO2 via novel ionic liquids
RSC Advances ( IF 3.9 ) Pub Date : 2022-08-02 , DOI: 10.1039/d2ra03966d
Anton Lindberg ₁ , Neil Vasdev _{1,

2}

Affiliation

Novel ionic liquids based on DBU and DBN halide salts were developed as a catalytic system for ring-opening of non-activated aziridines with [¹¹C]CO₂. The ability of ionic liquids to activate aziridines represents a simple methodology for the synthesis of ¹¹C-carbamates and can be extended for CO₂-fixation in organic and radiochemistry.

中文翻译：

[11C]CO2通过新型离子液体开环非活化氮丙啶

开发了基于 DBU 和 DBN 卤化物盐的新型离子液体作为催化体系，用于用 [ ¹¹ C]CO ₂对未活化的氮丙啶进行开环。离子液体激活氮丙啶的能力代表了一种合成¹¹ C-氨基甲酸酯的简单方法，并且可以扩展到有机化学和放射化学中的 CO _2固定。

更新日期：2022-08-02

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11