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Hypervalent Iodine-Mediated Azidation Reactions
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-28 , DOI: 10.1002/ejoc.202200754 Irina A. Mironova 1 , Stefan F. Kirsch 2 , Viktor Zhdankin 3 , Akira Yoshimura 4 , Mekhman S. Yusubov 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-28 , DOI: 10.1002/ejoc.202200754 Irina A. Mironova 1 , Stefan F. Kirsch 2 , Viktor Zhdankin 3 , Akira Yoshimura 4 , Mekhman S. Yusubov 1
Affiliation
Recently developed approaches to direct, one-step synthesis of various organic azides using hypervalent iodine reagents are summarized. Particularly useful azidating reagents are the stable azidobenziodoxoles that allow selective direct azidation of C−H single bonds or carbon-carbon double bonds under mild reaction conditions.
中文翻译:
高价碘介导的叠氮化反应
总结了最近开发的使用高价碘试剂直接一步合成各种有机叠氮化物的方法。特别有用的叠氮化试剂是稳定的叠氮苯并氧杂环戊烷,它允许在温和的反应条件下选择性地直接叠氮化 C-H 单键或碳-碳双键。
更新日期:2022-07-28
中文翻译:
高价碘介导的叠氮化反应
总结了最近开发的使用高价碘试剂直接一步合成各种有机叠氮化物的方法。特别有用的叠氮化试剂是稳定的叠氮苯并氧杂环戊烷,它允许在温和的反应条件下选择性地直接叠氮化 C-H 单键或碳-碳双键。