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Copper-Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Allyl Bromides with Organolithium Compounds
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-27 , DOI: 10.1002/ejoc.202200860 Jun Li 1 , Xiao Song 1 , Fusong Wu 1 , Hengzhi You 2 , Fen-Er Chen 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-27 , DOI: 10.1002/ejoc.202200860 Jun Li 1 , Xiao Song 1 , Fusong Wu 1 , Hengzhi You 2 , Fen-Er Chen 1
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Cu-catalyzed AAA reactions employing racemic cyclic allylic bromide and extremely reactive organolithium reagents as reaction partners have been disclosed. The corresponding alkylated products were obtained with high enantioselectivities (up to 98 % ee).
中文翻译：
铜催化外消旋环烯丙基溴与有机锂化合物的不对称烯丙基烷基化反应
已经公开了使用外消旋环状烯丙基溴和极活泼的有机锂试剂作为反应伙伴的铜催化的 AAA 反应。获得了具有高对映选择性（高达 98% ee）的相应烷基化产物。
更新日期：2022-07-27
中文翻译：
铜催化外消旋环烯丙基溴与有机锂化合物的不对称烯丙基烷基化反应
已经公开了使用外消旋环状烯丙基溴和极活泼的有机锂试剂作为反应伙伴的铜催化的 AAA 反应。获得了具有高对映选择性（高达 98% ee）的相应烷基化产物。
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