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Direct Functionalization of Lithium Phosphine Oxides Bearing an Alkyne Chain
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-26 , DOI: 10.1002/ejoc.202200738 Hamdi Sanaa 1 , Ali Samarat 2 , Muriel Durandetti 3
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2022-07-26 , DOI: 10.1002/ejoc.202200738 Hamdi Sanaa 1 , Ali Samarat 2 , Muriel Durandetti 3
Affiliation
Selective hydrophosphorylation of carbonyl bonds was developed via a lithium phosphine oxide intermediate, resulting in intermolecular addition to an aldehyde, instead of the intramolecular cyclisation pathway. Valuable alkynyl phosphorated alcohols were obtained in good yields and moderate diastereoselectivity.
中文翻译:
具有炔烃链的锂磷化氢的直接功能化
羰基键的选择性氢化磷酸化是通过氧化膦锂中间体开发的,导致醛的分子间加成,而不是分子内环化途径。以良好的收率和中等的非对映选择性获得了有价值的炔基磷酸醇。
更新日期:2022-07-26
中文翻译:
具有炔烃链的锂磷化氢的直接功能化
羰基键的选择性氢化磷酸化是通过氧化膦锂中间体开发的,导致醛的分子间加成,而不是分子内环化途径。以良好的收率和中等的非对映选择性获得了有价值的炔基磷酸醇。