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Electronic buffers make reaction milder: When magic C60 encounters copper
Chem ( IF 19.1 ) Pub Date : 2022-07-22 , DOI: 10.1016/j.chempr.2022.06.021
Hairong Yue , Xinbin Ma , Jinlong Gong

The required high hydrogen pressures remain a grand challenge for the practical application of hydrogenation reactions. Recently in Science, Zheng et al. reported a novel C60-buffered Cu/SiO2 catalyst, where C60 can act as an electron buffer for Cu/SiO2 to stabilize Cu+ species and lead to ambient-pressure synthesis of ethylene glycol.



中文翻译:

电子缓冲器使反应更温和:当魔法 C60 遇到铜时

所需的高氢气压力对于加氢反应的实际应用仍然是一个巨大的挑战。最近在《科学》杂志上,郑等人。报道了一种新型 C 60缓冲的 Cu/SiO 2催化剂,其中 C 60可以作为 Cu/SiO 2的电子缓冲剂以稳定 Cu +物质并导致乙二醇的环境压力合成。

更新日期:2022-07-22
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