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Investigation of Rotating Arc-Catalytic Reactor for CF4 Removal with High Energy Efficiency
Plasma Chemistry and Plasma Processing ( IF 2.6 ) Pub Date : 2022-07-22 , DOI: 10.1007/s11090-022-10274-y
Sungkwon Jo , Donghyun Cho , Dae Hoon Lee , Woo Seok Kang

CF4 is commonly used in semiconductor industries, and its removal requires a large amount of energy because it is a highly stable perfluorinated compound. In this study, a rotating arc-catalytic reactor that uses thermal plasma as the heat source for catalysts is introduced as an efficient method for CF4 removal. An AC rotating arc plasma was used with the catalyst for CF4 removal, and the plasma and catalyst were configured serially in this reactor. Destruction and removal efficiency (DRE) of CF4 and the energy efficiency of the removal process were experimentally investigated in the input power range of 2–3 kW and a steam-to-CF4 molar ratio of up to 20. The obtained results suggest that the DRE of CF4 was up to 98% and the energy efficiency was as high as 36.1 g/kWh, which is approximately 3.5 times higher than that obtained using a rotating arc reactor alone. In addition, the thermal efficiency was estimated to be approximately 67%, based on the temperatures of the inlet and outlet gases of the rotating arc-catalytic reactor. Thus, further improvement in the performance can be expected through subsequent thermal management and system optimization. These results confirm that using rotating arc-catalytic reactors is an energy-efficient strategy for application as scrubber systems to remove CF4.



中文翻译:

旋转电弧催化反应器高能效脱除CF4的研究

CF 4常用于半导体工业,由于它是一种高度稳定的全氟化合物,其去除需要大量的能量。在这项研究中,介绍了一种使用热等离子体作为催化剂热源的旋转电弧催化反应器,作为去除CF 4的有效方法。交流旋转电弧等离子体与催化剂一起用于CF 4去除,等离子体和催化剂在该反应器中串联配置。在 2-3 kW 的输入功率范围和高达 20 的蒸汽与 CF 4的摩尔比下,对 CF 4的破坏和去除效率(DRE)和去除过程的能量效率进行了实验研究。获得的结果表明CF 的 DRE4高达 98%,能量效率高达 36.1 g/kWh,比单独使用旋转电弧反应器获得的能量效率高约 3.5 倍。此外,根据旋转电弧催化反应器的入口和出口气体的温度,估计热效率约为 67%。因此,可以通过后续的热管理和系统优化来进一步提高性能。这些结果证实,使用旋转电弧催化反应器作为洗涤器系统去除CF 4是一种节能策略。

更新日期:2022-07-22
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