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Interfacial-engineered CoTiO3-based composite for photocatalytic applications: a review
Environmental Chemistry Letters ( IF 15.0 ) Pub Date : 2022-07-20 , DOI: 10.1007/s10311-022-01472-3
Nathasya Imanuella , Thongthai Witoon , Yoke Wang Cheng , Chi Cheng Chong , Kim Hoong Ng , I. Made Gunamantha , Dai-Viet N. Vo , Anh Tuan Hoang , Yuekun Lai

Photocatalysis is a green chemical process that could partly solve energy and pollution issues. Catalysts such as cobalt titanate, CoTiO3, have intrigued scientists due to a visible light-responsive band gap of about 2.3 eV and a high valance band potential of about 2.35 eV that allow a remarkable oxidative activity. Nonetheless, CoTiO3 photocatalytic activity is limited by charge recombination, thus requiring modifications. For instance, the introduction of a second semiconductor allows improved charge separation and notable enhancement of the activity. Here we review interfacial engineering of CoTiO3 by introduction of a second semiconductor. We describe the synthesis and photocatalytic applications of bare and modified CoTiO3. Modified CoTiO3 composites are categorized into Type-I, Type-II, Z-scheme, and S-scheme heterojunctions, depending on the band structures of the composite.



中文翻译:

用于光催化应用的界面工程 CoTiO3 基复合材料:综述

光催化是一种绿色化学过程,可以部分解决能源和污染问题。诸如钛酸钴、CoTiO 3等催化剂由于具有约 2.3 eV 的可见光响应带隙和约 2.35 eV 的高价带电位而引起了科学家的极大兴趣,从而具有显着的氧化活性。尽管如此,CoTiO 3光催化活性受到电荷复合的限制,因此需要进行修改。例如,引入第二种半导体可以改善电荷分离并显着提高活性。在这里,我们通过引入第二种半导体来回顾 CoTiO 3的界面工程。我们描述了裸和改性 CoTiO 3的合成和光催化应用. 改性CoTiO 3复合材料根据复合材料的能带结构分为I型、II型、Z型和S型异质结。

更新日期:2022-07-22
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