One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne,Chemistry - A European Journal

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One-Pot Synthesis of High-Strained Metal Vinylidene and Metal Carbyne
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-07-12 , DOI: 10.1002/chem.202201229
Fanping Huang _{1,

2} , Zhewei Yan ₁ , Xuejuan Zheng ₂ , Yapeng Cai ₁ , Hong Zhang ₁ , Haiping Xia _{1,

2}

Affiliation

A cyclic metal vinylidene with high ring-strain was obtained via a one-pot synthesis. The reactivity of this metal vinylidene with nucleophiles and electrophiles was investigated, resulting in unprecedented conversion of the metal vinylidene to a metal carbyne in five-membered ring.

中文翻译：