当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Reductive Cross-Coupling of α-Oxy Halides Enabled by Thermal Catalysis, Photocatalysis, Electrocatalysis, or Mechanochemistry
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2022-07-11 , DOI: 10.1002/anie.202204212
Chen Zhu 1 , Shao-Chi Lee 1 , Haifeng Chen 1 , Huifeng Yue 1 , Magnus Rueping 1
Affiliation  

The development of methods to access alcohol derivatives is one of the main concerns of considerable research. Herein, a nickel-catalyzed reductive cross-coupling reaction of α-oxy halides is reported with a series of C(sp2)- and C(sp)-electrophiles, including aryl halides, vinyl bromides, alkynyl bromides, and acyl chlorides with the use of a metal reductant, photocatalysis, electrochemistry, and mechanochemistry.

中文翻译:

通过热催化、光催化、电催化或机械化学实现 α-卤氧化物的还原交叉偶联

获得醇衍生物的方法的开发是大量研究的主要关注点之一。在此,报道了 α-卤氧化物与一系列 C( sp 2 )-和 C( sp )-亲电试剂的镍催化还原交叉偶联反应,包括芳基卤化物、溴乙烯、炔基溴化物和酰氯。使用金属还原剂、光催化、电化学和机械化学。
更新日期:2022-07-11
down
wechat
bug