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Synthesis and supercapacitive behaviour of SnO2/r-GO nanocomposite
Synthetic Metals ( IF 4.0 ) Pub Date : 2022-07-08 , DOI: 10.1016/j.synthmet.2022.117132
Naveen Chandra Joshi , B.S. Rawat , Himanshu Bisht , Vikash Gajraj , Niraj Kumar , S. Chetana , Prateek Gururani

In this work, we have used Camellia sinensis leaves extract in the synthesis of SnO2 NPs. The biologically synthesised SnO2 NPs were combined with reduced graphene oxide (r-GO) to produce SnO2/r-GO under ultrasonic conditions. The extract-based synthetic method was found to be environmentally safe, less time-consuming, and efficient. According to phyto-chemical screening, the biologically active components such as terpenoids, phyto-sterols, carbohydrates, amino acids, alkaloids, tannins, and flavonoids, respectively, were present in Camellia sinensis leaves extract. Various analytical techniques have been used to investigate the SnO2/r-GO. FTIR analysis indicated the presence of O-H, Cdouble bondC, Sn-O, Sn-C, etc. bonds on the surface of green and ultrasonically based SnO2/r-GO. The crystalline nature of SnO2/r-GO has been confirmed by XRD pattern. Further, the freshly synthesised SnO2/r-GO has been utilised as a supercapacitor material. The specific capacitances of the cost-effective SnO2/r-GO were found to be 310.7 F g−1 at an initial scan rate (10 mV s−1) and 267.8 F g−1 at an initial current density (1 A g−1), respectively. The specific energy and specific power were evaluated as 13.3 Wh kg−1 and 160.6 W kg−1 at 1 A g−1, and 4.6 Wh kg−1 and 1606.2 W kg−1 at 10 A g−1, respectively.



中文翻译:

SnO2/r-GO纳米复合材料的合成及超电容行为

在这项工作中,我们在 SnO 2 NPs的合成中使用了山茶叶提取物。将生物合成的 SnO 2 NPs 与还原氧化石墨烯 (r-GO) 结合,在超声波条件下产生 SnO 2 /r-GO。发现基于提取物的合成方法对环境安全、耗时少且高效。经植物化学筛选,山茶叶提取物中分别含有萜类、植物甾醇、碳水化合物、氨基酸、生物碱、单宁和黄酮等生物活性成分各种分析技术已被用于研究 SnO 2/r-开始。FTIR分析表明,绿色和超声基SnO 2 /r-GO双键表面存在OH、C C、Sn-O、Sn-C等键。SnO 2 /r-GO的结晶性质已通过 XRD 图案得到证实。此外,新合成的 SnO 2 /r-GO 已被用作超级电容器材料。发现具有成本效益的 SnO 2 /r-GO的比电容在初始扫描速率 (10 mV s -1 )下为 310.7 F g -1 ,在初始电流密度 (1 A g -1 ),分别。比能量和比功率被评估为13.3 Wh kg -1和160.6 W kg -1分别在 1 A g -1和 4.6 Wh kg -1和 1606.2 W kg -1在 10 A g -1下。

更新日期:2022-07-09
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