A reliable thermal-derived method for spatially and temporally continuous latent heat flux (LE) estimates is vital for agricultural water resource management. In this study, we proposed a novel three-source LE model (TSLEM) derived by all-weather thermal infrared (TIR) land surface temperature (LST) to generate all-sky daily LE in mainland China. In this approach, LE was partitioned into the energy fluxes from canopy transpiration, soil evaporation, and interception water evaporation, respectively. Importantly, a new strategy was used to decompose radiational temperature into soil temperature (T_s), canopy temperature (T_c) and interception water temperature (T_i). Then soil evaporation was estimated by Penman-Monteith (PM) equation that parameterizes a soil resistance as a function of the normalized difference temperature index (NDTI) derived from T_s. A simplified MOD16 algorithm framework was used to estimate canopy transpiration and a Priestley-Taylor (PT) model to estimate interception evaporation. The proposed method was validated using 26 eddy covariance (EC) tower sites in mainland China across various vegetation types and applied to generate spatial continuous daily LE in mainland China. The results show that TSLEM accurately yielded daily LE with an average coefficient of determination (R²) of 0.53 (p<0.01) and root-mean-square-error (RMSE) of 27.37 W/m², indicating TSLEM is a promising method for generating daily LE using all-weather LST at the regional scale.