The development of CO₂ into hydrocarbon fuels has emerged as a green method that could help mitigate global warning. The novel structured photocatalyst is a promising material for use in a photocatalytic and magneto-electrochemical method that fosters the reduction of CO₂ by suppressing the recombination of electron—hole pairs and effectively transferring the electrons to the surface for the chemical reaction of CO₂ reduction. In our study, we have developed a novel-structured AgCuZnS₂—graphene—TiO₂ to analyze its catalytic activity toward the selective evolution of CO₂. The selectivity of each nanocomposite substantially enhanced the activity of the AgCuZnS₂—graphene—TiO₂ ternary nanocomposite due to the successful interaction, and the selectivity of the final product was improved to a value 3 times higher than that of the pure AgCuZnS₂ and 2 times higher than those of AgCuZnS₂—graphene and AgCuZnS₂—TiO₂ under ultraviolet (UV)-light (λ = 254 nm) irradiation in the photocatalytic process. The electrochemical CO₂ reduction test was also conducted to analyze the efficacy of the AgCuZnS₂—graphene—TiO₂ when used as a working electrode in laboratory electrochemical cells. The electrochemical process was conducted under different experimental conditions, such as various scan rates (mV·s⁻¹), under UV-light and with a 0.07 T magnetic-core. The evolution of CO₂ substantially improved under UV-light (λ = 254 nm) and with 0.07 T magnetic-core treatment; these improvements were attributed to the facts that the UV-light activated the electron-transfer pathway and the magnetic core controlled the pathway of electron-transmission/prevention to protect it from chaotic electron movement. Among all tested nanocomposites, AgCuZnS₂—graphene—TiO₂ absorbed the CO₂ most strongly and showed the best ability to transfer the electron to reduce the CO₂ to methanol. We believe that our newly-modeled ternary nanocomposite opens up new opportunities for the evolution of CO₂ to methanol through an electrochemical and photocatalytic process.

将 CO ₂开发成碳氢化合物燃料已成为一种有助于减轻全球警告的绿色方法。这种新型结构光催化剂是一种很有前途的材料，可用于光催化和磁电化学方法，通过抑制电子-空穴对的复合并有效地将电子转移到表面进行 CO 2 还原的化学反应来促进 CO _2的还原。 . 在我们的研究中，我们开发了一种新型结构的AgCuZnS ₂ -石墨烯-TiO ₂来分析其对CO ₂选择性演化的催化活性。每种纳米复合材料的选择性显着增强了 AgCuZnS _2的活性—石墨烯—TiO ₂三元纳米复合材料由于成功的相互作用，最终产物的选择性提高到纯AgCuZnS _{2的3倍和AgCuZnS 2}的2倍—石墨烯和AgCuZnS ₂ — TiO ₂在光催化过程中在紫外 (UV) 光 ( λ = 254 nm) 照射下。还进行了电化学CO ₂还原试验以分析AgCuZnS ₂ -石墨烯-TiO _{2的功效。}在实验室电化学电池中用作工作电极时。电化学过程是在不同的实验条件下进行的，例如各种扫描速率（mV·s ^{- 1}）、紫外光和 0.07 T 磁芯。在紫外光 ( λ = 254 nm) 和 0.07 T 磁芯处理下，CO _{2的释放显着改善；}这些改进归因于紫外光激活了电子转移路径，而磁芯控制了电子传输/阻止路径以保护其免受混乱电子运动的影响。在所有测试的纳米复合材料中，AgCuZnS ₂ -石墨烯-TiO ₂吸收了CO ₂最强烈并显示出最好的电子转移能力以将CO ₂还原为甲醇。我们相信，我们新建模的三元纳米复合材料为通过电化学和光催化过程将 CO ₂转化为甲醇开辟了新的机遇。