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Scintillation and photoluminescence investigations of Gd2MoB2O9: CeF3 phosphors
Radiation Physics and Chemistry ( IF 2.8 ) Pub Date : 2022-06-27 , DOI: 10.1016/j.radphyschem.2022.110368
W. Wongwan , P. Yasaka , K. Boonin , A. Angnanon , K. Duangjai , W. Sa-ardsin , S. Kothan , J. Kaewkhao

The CeF3 doped Gd2-xMoB2O9 phosphors (where x = 0.00, 0.25, 0.50 and 0.75 mol%) were synthesized by the conventional high-temperature solid-state reaction method at 900 °C for 12 h in air. DSC and TGA analysis executed to study the optimum temperature for sintering. The structural, photoluminescence and X-ray luminescence properties were investigated. The structure of the samples was analyzed by using X-ray diffractometer (XRD). The absorption spectra were analyzed and found that absorption edge increased with the increasing concentration of CeF3. The photoluminescence of phosphors shows the overlapping of excitation and emission peaks in the range of 300 nm–450 nm. These emission peak correspond to the 5d – 4f transitions of Ce3+ ion. The optimum concentration of CeF3 in these phosphors is 0.50 mol% corresponding to maximum emission intensity. The X-ray induced optical luminescence spectra showed a strong emission peak at 411 nm the concentration quenching at 0.75 mol%, which is as efficient as 54.4% compared with bismuth germanium oxide (BGO) crystal. The luminescence decay increased with the increment of CeF3 concentration. From the optical properties investigated, it was found that the phosphors performed a strong and fast luminescence signal which is appropriate for the development of scintillators in X-ray detector devices.



中文翻译:

Gd2MoB2O9: CeF3 荧光粉的闪烁和光致发光研究

CeF 3掺杂的Gd 2-x MoB 2 O 9荧光粉(其中x = 0.00, 0.25, 0.50和0.75 mol%)通过常规高温固态反应方法在900℃下在空气中合成12小时。进行 DSC 和 TGA 分析以研究烧结的最佳温度。研究了结构、光致发光和X射线发光特性。使用X射线衍射仪(XRD)分析样品的结构。对吸收光谱进行分析发现,随着CeF 3浓度的增加,吸收边增加。. 荧光粉的光致发光显示激发和发射峰在 300 nm-450 nm 范围内的重叠。这些发射峰对应于 Ce 3+离子的 5d – 4f 跃迁。这些荧光粉中CeF 3的最佳浓度为0.50 mol%,对应于最大发射强度。X 射线诱导的发光光谱在 411 nm 处显示出强烈的发射峰,浓度猝灭为 0.75 mol%,与铋锗氧化物 (BGO) 晶体相比,效率高达 54.4%。发光衰减随着CeF 3的增加而增加专注。根据所研究的光学特性,发现磷光体发出强烈且快速的发光信号,这适用于 X 射线探测器设备中闪烁体的开发。

更新日期:2022-07-01
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