当前位置: X-MOL 学术Geotherm. Energy › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Dissolved organic compounds in geothermal fluids used for energy production: a review
Geothermal Energy ( IF 2.9 ) Pub Date : 2022-06-25 , DOI: 10.1186/s40517-022-00220-8
Alessio Leins , Danaé Bregnard , Andrea Vieth-Hillebrand , Pilar Junier , Simona Regenspurg

Dissolved organic matter (DOM) can be found in a variety of deep subsurface environments such as sedimentary basins, oil fields and mines. However, the origin, composition and fate of DOM within deep geothermal reservoirs used for energy production is relatively unknown. With well depths reaching a few kilometers, these sites give access to investigate deep subsurface environments. Natural DOM as well as artificial DOM (e.g., from chemical scaling inhibitors) might serve as nutrients for microorganisms or affect chemical properties of the fluids by complexation. Its composition might reveal hydraulic connections to organic-rich strata, giving insights to the fluid flow within the reservoir. This review presents an overview of a total of 143 fluid samples from 22 geothermal sites (mainly central Europe), from the literature and compiling data to address the importance of DOM in geothermal fluids and how it might affect geothermal operation. The environmental conditions of the sites included varied greatly. Temperatures range from 34 to $$200\,^{\circ }\hbox {C}$$ , depths from 850 to 5000 m, chloride content from 0.1 to $$160\,{\hbox {g}\,\hbox {L}^{-1}}$$ , and dissolved organic carbon (DOC) concentrations from 0.1 to $$30.1\,{\hbox {g}\,\hbox {L}^{-1}}$$ . The DOC concentrations were found to be generally lower in the fluids with temperatures below $$80\,{}^{\circ }\hbox {C}$$ . DOC concentrations were higher in fluids with temperatures above $$80\,{}^{\circ }\hbox {C}$$ and showed a decrease towards $$200\,{}^{\circ }\hbox {C}$$ . Microbial degradation might be the main driver for low DOC concentrations in the lower temperature range (below $$80\,{}^{\circ }\hbox {C}$$ ), while thermal degradation likely accounts for the decline in DOC in the temperature region between $$80\,{}^{\circ }\hbox {C}$$ and $$200\,{}^{\circ }\hbox {C}$$ . This review shows that DOM can be found in a variety of geothermal reservoirs and that it could be an additional essential tool to better understand fluid chemistry and reservoir conditions, and to optimize geothermal operation.

中文翻译:

用于能源生产的地热流体中溶解的有机化合物:综述,用于能源生产的地热流体中溶解的有机化合物:综述

溶解有机物 (DOM) 可以在各种深层地下环境中找到,例如沉积盆地、油田和矿山。然而,用于能源生产的深层地热储层中 DOM 的来源、组成和归宿相对未知。这些站点的井深达到几公里,可以研究深层地下环境。天然 DOM 和人工 DOM(例如,来自化学结垢抑制剂)可能作为微生物的营养物质或通过络合影响流体的化学性质。它的成分可能揭示与富含有机物地层的水力联系,从而深入了解储层内的流体流动。本综述概述了来自 22 个地热站点(主要是中欧)的 143 个流体样本,来自文献和汇编数据,以解决 DOM 在地热流体中的重要性以及它如何影响地热运行。包括的站点的环境条件差异很大。温度范围从 34 到 $$200\,^{\circ }\hbox {C}$$ ,深度从 850 到 5000 m,氯化物含量从 0.1 到 $$160\,{\hbox {g}\,\hbox {L }^{-1}}$$ 和溶解有机碳 (DOC) 浓度从 0.1 到 $$30.1\,{\hbox {g}\,\hbox {L}^{-1}}$$ 。发现温度低于 $$80\,{}^{\circ }\hbox {C}$$ 的流体中 DOC 浓度通常较低。温度高于 $$80\,{}^{\circ }\hbox {C}$$ 的流体中 DOC 浓度较高,并在接近 $$200\,{}^{\circ }\hbox {C}$$ 时下降. 微生物降解可能是较低温度范围内(低于 $$80\,{}^{\circ }\hbox {C}$$ )的低 DOC 浓度的主要驱动因素,而热降解可能是导致 DOC 下降的原因$$80\,{}^{\circ }\hbox {C}$$ 和 $$200\,{}^{\circ }\hbox {C}$$ 之间的温度区域。这篇综述表明,DOM 可以在各种地热储层中找到,它可以成为更好地了解流体化学和储层条件以及优化地热运行的额外重要工具。,溶解有机物 (DOM) 可以在各种深层地下环境中找到,例如沉积盆地、油田和矿山。然而,用于能源生产的深层地热储层中 DOM 的来源、组成和归宿相对未知。这些站点的井深达到几公里,可以研究深层地下环境。天然 DOM 和人工 DOM(例如,来自化学结垢抑制剂)可能作为微生物的营养物质或通过络合影响流体的化学性质。它的成分可能揭示与富含有机物地层的水力联系,从而深入了解储层内的流体流动。本综述概述了来自 22 个地热站点(主要是中欧)的 143 个流体样本,来自文献和汇编数据,以解决 DOM 在地热流体中的重要性以及它如何影响地热运行。包括的站点的环境条件差异很大。温度范围从 34 到 $$200\,^{\circ }\hbox {C}$$ ,深度从 850 到 5000 m,氯化物含量从 0.1 到 $$160\,{\hbox {g}\,\hbox {L }^{-1}}$$ 和溶解有机碳 (DOC) 浓度从 0.1 到 $$30.1\,{\hbox {g}\,\hbox {L}^{-1}}$$ 。发现温度低于 $$80\,{}^{\circ }\hbox {C}$$ 的流体中 DOC 浓度通常较低。温度高于 $$80\,{}^{\circ }\hbox {C}$$ 的流体中 DOC 浓度较高,并在接近 $$200\,{}^{\circ }\hbox {C}$$ 时下降. 微生物降解可能是较低温度范围内(低于 $$80\,{}^{\circ }\hbox {C}$$ )的低 DOC 浓度的主要驱动因素,而热降解可能是导致 DOC 下降的原因$$80\,{}^{\circ }\hbox {C}$$ 和 $$200\,{}^{\circ }\hbox {C}$$ 之间的温度区域。这篇综述表明,DOM 可以在各种地热储层中找到,它可以成为更好地了解流体化学和储层条件以及优化地热运行的额外重要工具。
更新日期:2022-06-27
down
wechat
bug