Redox-Active Crystalline Coordination Catalyst for Hybrid Electrocatalytic Methanol Oxidation and CO2 Reduction,Angewandte Chemie International Edition

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Redox-Active Crystalline Coordination Catalyst for Hybrid Electrocatalytic Methanol Oxidation and CO2 Reduction
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-24 , DOI: 10.1002/anie.202207282
Sheng-Nan Sun ₁ , Long-Zhang Dong ₁ , Jia-Ru Li ₁ , Jing-Wen Shi ₁ , Jiang Liu ₁ , Yi-Rong Wang ₁ , Qing Huang ₁ , Ya-Qian Lan ₁

Affiliation

The transfer of electrons from electron-rich metal clusters (oxidation active sites) to electron-deficient metalloporphyrins (reduction active sites) leads to stronger oxidizability of Ni₈ clusters and stronger reducibility of metalloporphyrin. The enhanced oxidizability of Ni₈ and reducibility of metalloporphyrin, therefore, result in improved methanol electrooxidation and CO₂ electroreduction with the bifunctional crystalline coordination catalyst.

中文翻译：

用于混合电催化甲醇氧化和二氧化碳还原的氧化还原活性晶体配位催化剂

电子从富电子金属簇（氧化活性位点）向缺电子金属卟啉（还原活性位点）的转移导致Ni ₈簇的氧化性更强，金属卟啉的还原性更强。_{因此，Ni 8}的增强氧化性和金属卟啉的还原性导致使用双功能结晶配位催化剂改善甲醇电氧化和CO _{2电还原。}

更新日期：2022-06-24

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