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Solvent-Dependent Supramolecular Host–Guest Assemblies of Platinum(II) Tweezers and a Guest System: From Discrete Molecules to High-Ordered Oligomers
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-06-24 , DOI: 10.1002/anie.202207313
Jenny Yuk-Wa Yeung 1 , Fred Ka-Wai Kong 1 , Franky Ka-Wah Hau 1 , Michael Ho-Yeung Chan 1 , Maggie Ng 1 , Ming-Yi Leung 1 , Vivian Wing-Wah Yam 1
Affiliation  

The host–guest assembly process of a platinum(II) tweezers–guest system can be controlled by varying the solvent composition. The change in the assembly behavior from discrete host and guest molecules to high-ordered host–guest oligomers can be probed by drastic changes in the color from yellow to orange to green, demonstrating a three-state supramolecular system with potential application as a colorimetric micro-environment sensor.

中文翻译:

铂 (II) 镊子和客体系统的溶剂依赖性超分子主客体组件:从离散分子到高阶低聚物

铂(II)镊子-客体系统的主客体组装过程可以通过改变溶剂组成来控制。可以通过颜色从黄色到橙色到绿色的剧烈变化来探测从离散的主客体分子到高有序主客体低聚物的组装行为的变化,证明了一种具有潜在应用的三态超分子系统作为比色微-环境传感器。
更新日期:2022-06-24
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