Recent advances in the transformations of different types of Stemona alkaloids,Organic Chemistry Frontiers

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Recent advances in the transformations of different types of Stemona alkaloids
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2022-06-24 , DOI: 10.1039/d2qo00789d
Tao Shi ₁ , Xiaodong Wang ₁ , Jinhong Chen ₁ , Fei Cao ₁ , Gaofeng Yin ₁ , Yao-Fu Zeng ₂ , Zhen Wang _{1,

2}

Affiliation

In recent years, researches on the total syntheses of Stemona alkaloids with different 5/7 bicyclic systems have attracted increasing attention, and the development momentum in this field has gradually changed from single molecule synthesis to unified syntheses of multiple molecules. Among them, the emergence of mutual transformations among Stemona alkaloids with different ring systems has indeed improved the synthetic efficiency toward diverse alkaloids. In continuation of our synthetic blueprint on Stemona alkaloids and to provide inspiration for discovering more efficient synthesis strategies, we summarized the recent advances in the transformations of different types of Stemona alkaloids and discussed the future of this domain.

中文翻译：

不同类型百部生物碱转化的新进展

近年来，不同5/7双环体系百部生物碱的全合成研究越来越受到关注，该领域的发展势头逐渐由单分子合成向多分子统一合成转变。其中，不同环系百部生物碱相互转化的出现，确实提高了多种生物碱的合成效率。为延续我们关于百部生物碱的合成蓝图并为发现更有效的合成策略提供灵感，我们总结了不同类型百部生物碱转化的最新进展，并讨论了该领域的未来。

更新日期：2022-06-24

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