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Investigation of PCBM/ZnO and C60/BCP-based electron transport layer for high-performance p-i-n perovskite solar cells
Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2022-06-22 , DOI: 10.1016/j.jallcom.2022.166007
Hyun-Jung Lee , Seok-In Na

The objective of this study was to comprehensively investigate and compare PCBM/ZnO and C60/BCP-based electron transport layers (ETLs) (well recognized as representative ETLs) between perovskite and metal electrode in perovskite solar cells (PeSCs) for high-performance p-i-n structure PeSCs. Their film characteristics and their effects on solar cell performances were studied. When PCBM/ZnO was used as ETL material, the PCE of PeSCs was 19.36 %, which was higher than the PCE of 17.10 % when C60/BCP was used possibly due to more efficient charge recombination reduction and charge extraction shown in PCBM/ZnO-based devices. However, in terms of stability (air, light-soaking, and heat), C60/BCP-based devices showed higher stability than PCBM/ZnO-based devices.



中文翻译:

用于高性能pin钙钛矿太阳能电池的PCBM/ZnO和C60/BCP基电子传输层的研究

本研究的目的是全面研究和比较钙钛矿太阳能电池 (PeSC) 中钙钛矿和金属电极之间基于 PCBM/ZnO 和 C 60 /BCP 的电子传输层 (ETL)(公认的代表性 ETL),以实现高性能引脚结构 PeSCs。研究了它们的薄膜特性及其对太阳能电池性能的影响。当 PCBM/ZnO 用作 ETL 材料时,PeSCs 的 PCE 为 19.36 %,高于使用 C 60 /BCP 时 17.10 % 的 PCE,这可能是由于 PCBM/ZnO 中更有效的电荷复合减少和电荷提取- 基于设备。然而,在稳定性(空气、光浸泡和热)方面,基于 C 60 /BCP 的器件表现出比基于 PCBM/ZnO 的器件更高的稳定性。

更新日期:2022-06-22
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