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Ammonia sensing characteristics of a cerium oxide thin film coated with platinum nanoparticles
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2022-06-21 , DOI: 10.1016/j.snb.2022.132241
Jing-Shiuan Niu , I-Ping Liu , Kuan-Hsiang Chen , Jung-Hui Tsai , Wei-Chou Hsu , Wen-Chau Liu

This paper reports on ammonia (NH3) sensing characteristics of a new semiconducting metal oxide (SMO) sensor. employing a cerium oxide (CeO2) thin film and platinum (Pt) nanoparticles (NPs) as a sensing layer. The thickness of CeO2 thin film is 30 nm and the particle size of Pt NPs is about 4–6 nm. Based on the enhanced surface area/volume (SA/V) ratio and catalytic ability of Pt metal, the sensing behaviors are efficiently improved owing to the smaller Pt NPs. A high sensing response of 5.81 under 1000 ppm NH3/air gas and a low detectable content of 1 ppm NH3/air are acquired at 275 ℃. In addition, a relatively fast sensing action with the response (recovery) times of 15 s (85 s) and 6 s (25 s) are observed upon exposure to 1000 and 1 ppm NH3/air gas, respectively, at 300 ℃. The Langmuir isotherm is used to study the related surface coverage under introduced ammonia gas. The proposed Pt NP/CeO2 sensor shows prominent stability for long-term operation without intentional passivation treatment. The proposed sensor device’s benefits include a simple device structure, relatively easy manufacturing, a wide sensing range of ammonia gas content (1–1000 ppm NH3/air), and lower cost.



中文翻译:

涂有铂纳米颗粒的氧化铈薄膜的氨传感特性

本文报道了一种新型半导体金属氧化物 (SMO) 传感器的氨 (NH 3 ) 传感特性。采用氧化铈 (CeO 2 ) 薄膜和铂 (Pt) 纳米粒子 (NPs) 作为传感层。CeO 2薄膜的厚度为30 nm,Pt NPs的粒径约为4-6 nm。基于 Pt 金属增强的表面积/体积 (S A /V) 比和催化能力,由于更小的 Pt NPs,传感行为得到有效改善。在 1000 ppm NH 3 /空气气体下具有 5.81 的高传感响应和 1 ppm NH 3的低可检测含量/空气在275℃下获得。此外,在 300 ℃ 分别暴露于 1000 和 1 ppm NH 3 /空气气体时,观察到响应(恢复)时间为 15 s (85 s) 和 6 s (25 s) 的相对快速的传感动作。Langmuir 等温线用于研究引入氨气下的相关表面覆盖率。所提出的 Pt NP/CeO 2传感器在无需有意钝化处理的情况下长期运行显示出显着的稳定性。所提出的传感器装置的优点包括简单的装置结构、相对容易的制造、广泛的氨气含量感测范围(1-1000 ppm NH 3 /空气)和较低的成本。

更新日期:2022-06-25
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