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Mathematical modeling of the co-decontamination process in PUREX
Journal of Radioanalytical and Nuclear Chemistry ( IF 1.5 ) Pub Date : 2022-06-21 , DOI: 10.1007/s10967-022-08377-z
Zifang Guo , Jia Tang , Yu Yang , Yunliang Lin , Geng Chen , Limin Jiao , Jiawei Lu , Mingzhang Lin

A mathematical model of co-decontamination process (1A) containing U(VI), Pu(IV), Zr(IV), and Ru(III) was developed with a high-performance Iteration of Extraction Equilibrium (ITEE) algorithm. ITEE algorithm not only guarantees the positive solution set but also possesses better computational efficiency than L-BFGS-B and fsolve algorithms. This model was used to study the effects of the HNO3 concentration and the location of the feed stage on the extraction and decontamination efficiencies. The results show HNO3 is beneficial to the extraction of U, Pu, and Zr. More extraction stages boost the extraction of U and Pu into the organic phase.



中文翻译:

PUREX 中协同净化过程的数学模型

使用高性能的萃取平衡迭代 (ITEE) 算法开发了包含 U(VI)、Pu(IV)、Zr(IV) 和 Ru(III) 的共净化过程 (1A) 的数学模型。ITEE算法不仅保证了正解集,而且比L-BFGS-B和fsolve算法具有更好的计算效率。该模型用于研究 HNO 3浓度和进料阶段位置对萃取和净化效率的影响。结果表明HNO 3有利于U、Pu和Zr的提取。更多的萃取阶段促进了 U 和 Pu 萃取到有机相中。

更新日期:2022-06-22
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