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Hydrogen embrittlement of high-strength API carbon steels in H2S and CO2 containing environments
Gas Science and Engineering Pub Date : 2022-06-22 , DOI: 10.1016/j.jngse.2022.104676
Jiwon Jeon , Ramadan Ahmed , Rida Elgaddafi , Catalin Teodoriu

This study aims to understand the Sulfide Stress Cracking (SSC) resistance of API carbon steels exposed to wet sour environments containing CO2. A mini-pipe specimen was cut from API grade tubulars and placed in an SSC test cell to perform the investigation. The specimen was highly strained and internally pressurized while exposed to the corrosive environment for seven days. The partial pressure ratio (PPR) of CO2 (i.e. ratio of partial pressure of CO2 to the total pressure) was varied to study the effect of CO2 content on SSC. Experiments were performed while maintaining a constant H2S concentration and temperature. The steels' variations in mechanical properties (ultimate tensile strength and plastic strain before failure) after exposure to the sour environment are used to quantify the embrittlement. In addition, the specimens were examined using optical microscopes to assess the severity of the SSC corrosion based on shear deformation patterns and crack features. The SSC resistance of the tested steels was minimized when the PPR of CO2 was approximately 20%. Results demonstrate that the materials have adequate SSC corrosion resistance to be utilized in the environment containing 280 ppm H2S. Nevertheless, their SSC resistance reduced noticeably between 10 and 30% PPR of CO2.



中文翻译:

高强度 API 碳钢在含 H2S 和 CO2 环境中的氢脆

本研究旨在了解API 碳钢暴露在含 CO 2的潮湿酸性环境中的抗硫化物应力开裂 (SSC) 性能。从 API 级管材上切下一个微型管样品,并放置在 SSC 测试单元中以进行研究。样品在腐蚀环境中暴露 7 天时受到高度应变和内部加压。改变CO 2的分压比(PPR)(即CO 2的分压与总压力的比)来研究CO 2含量对SSC的影响。在保持恒定 H 2的同时进行实验S 浓度和温度。暴露于酸性环境后钢的机械性能变化(最终抗拉强度和失效前的塑性应变)用于量化脆化。此外,使用光学显微镜检查试样,以根据剪切变形模式和裂纹特征评估 SSC 腐蚀的严重程度。当 CO 2约为 20%时,测试钢的 SSC 阻力最小化。结果表明,这些材料具有足够的 SSC 耐腐蚀性,可用于含有 280 ppm H2S 的环境中。然而,它们的 SSC 耐性显着降低了 10% 至 30% PPR 的 CO2

更新日期:2022-06-26
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